Boiler Water Treatment Chemical Guidelines—Part Il continued Because of the associated corrosion problems, chelants are not the preferred treatment choice. However, if the system dictates the use of chelating agents, it can feed under "starvation" conditions, i.e., no free residual in the boiler. Based on the trace level of hardness in the boiler
Read MoreAlkalinity. alkalinity is the quantity of dissolved earth minerals expressed as CaCO 3, Ca(HCO 3) 2 or Ca(OH) 2.It is an indicator of scale tendency . It is also an important factor for assess the risk of corrosion in water cooling system and boiler, since the higher alkalinity suggested lower corrosivity in water chemistry.
Read MoreIn modern boiler systems, dissolved oxygen is handled by first mechanically removing most of the dissolved oxygen and then chemically scavenging the remainder. The mechanical degasification is typically carried out with vacuum degasifiers that reduce oxygen levels to less than 0.5-1.0 mg/L or with deaerating heaters that reduce oxygen
Read MoreThe ideal pH for feedwater is between 7 and 9, slightly alkaline. To keep the water within this range, add sodium phosphate salts or sodium hydroxide. Unfortunately, you cannot directly monitor the pH inside the heat of the boiler. Rather, you must measure pH from a cooler, lower-pressure side stream.
Read MoreMaintenance of proper pH throughout the boiler feedwater, boiler, and condensate systems is essential for corrosion control. Most low-pressure boiler system operators monitor boiler water alkalinity because it correlates very closely with pH, while most feedwater, condensate, and high-pressure boiler water requires direct monitoring of pH.
Read Morehydrazine. Hydrazine is a strong reducing agent at FW and boiler temperatures, especially in the pH range 9 to 10.5. Typically, in CANDU reactors, hydrazine is added between the deaerator (DA) and the DA storage tank, to control FW oxygen. The thermal decomposition of hydrazine generates ammonia, which helps sustain a high pH.
Read MoreJan 07, 2021 · Standards related to corrosion and staining: Chloride, Copper, Corrosivity, Iron, Manganese, pH, Total Dissolved Solids, Zinc; Scaling and sedimentation are other processes which have economic impacts. Scale is a mineral deposit which builds up on the insides of hot water pipes, boilers, and heat exchangers, restricting or even blocking water flow.
Read MoreThe ideal pH for feedwater is between 7 and 9, slightly alkaline. To keep the water within this range, add sodium phosphate salts or sodium hydroxide. Unfortunately, you cannot directly monitor the pH inside the heat of the boiler. Rather, you must measure pH from a cooler, lower-pressure side stream.
Read MoreThe factors of scaling and corrosivity are not inversely related. There are, or can be causal relations between corrosivity and scaling for a given water, or even in general. But it is also true that there can be waters which are very non-scaling but also non-corrosive. For example, deionized water that is purged of oxygen, i.e. boiler feedwater.
Read MoreCauses, and prevention of corrosion in boilers, type of corrosion. Corrosion is the reversion of a metal to its ore form. Iron, for example, reverts to iron oxide as the result of corrosion. The process of corrosion, however is a complex electro chemical reaction and it takes many forms.
Read MoreIn modern boiler systems, dissolved oxygen is handled by first mechanically removing most of the dissolved oxygen and then chemically scavenging the remainder. The mechanical degasification is typically carried out with vacuum degasifiers that reduce oxygen levels to less than 0.5-1.0 mg/L or with deaerating heaters that reduce oxygen
Read MoreJun 12, 2018 · For typical steel/iron/cast iron, when the pH is less than about 4, protective oxide films tend to dissolve and corrosion rates increase. When the pH is between about 4 and 10, soil corrosion is independent of pH. When the pH is greater than 10, the metal becomes passive and corrosion rates decrease with increasing pH.
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